专利摘要:
Herbicidal compositions comprising, as active ingredient, a diphenyl ether derivative of formula <CHEM> wherein R1 represents a hydrogen or halogen atom or an alkyl or haloalkyl group; R2 and R3 each independently represents a hydrogen or halogen atom or an alkyl, haloalkyl, nitro or cyano group; and the substituents A and B have the meanings as defined in the text; the use of such diphenyl ethers as herbicides; certain novel diphenyl ethers within formula I and their preparation.
公开号:SU1314947A3
申请号:SU843822000
申请日:1984-11-29
公开日:1987-05-30
发明作者:Хаддок Эрнест;Томас Кларк Майкл;Джеймс Гилмор Ян
申请人:Шелл Интернэшнл Рисерч Маатсхаппий Б.В. (Фирма);
IPC主号:
专利说明:

113
This invention relates to chemical methods for controlling weeds and unwanted vegetation.
The aim of the invention is to increase the efficiency of the method of controlling undesirable vegetation based on the use of diphenyl ether derivatives.
8pcs 1 is a list of active substances.
The active substances are used in the form of preparations which are prepared by dissolving them in acetone containing O, A wt.% Of alkylphenyl polyoxyethylene ether, and diluting with water to a certain concentration.
Pre-emergence treatment.
Seeds of experimental plants are sown in prepared soil (garden loam) and treated with its liquid form of active substances. Plants are grown in a greenhouse for 12 days and evaluate the herbicidal effect on a scale from 0 to 9.
O - no damage;
9- full plant death; 1-8 - intermediate values
(1 point corresponds to about 10%).
The results of the experiments are presented in table. 3, Compound numbers correspond to the numbers in the table. one.
Post-harvest processing.
Experimental plants grown under greenhouse conditions to a certain stage are treated with active substance preparations in two ways: by irrigating the soil under the plants and spraying the foliage of the plants. The evaluation of the herbicidal effect was carried out 12 days after spraying the foliage and 13 days after irrigating the soil. The rating scale is presented above. The results of the experiments are presented in table. 2 and 3.
Post-harvest processing (comparative experience).
Experienced plants grown in. A greenhouse, before a certain growth stage, is treated with preparations of experimental substances and, after a certain time after treatment (12-14 days), the herbicidal effect is evaluated. The evaluation is carried out using a computer program.
This program analyzes the selectivity distribution model in which compounds were tested for various plants. The analysis assumes the same distribution of selectivity for all compounds, but at different levels of non-active7 2
nosti. Accepted by the same selectivity distribution, the program calculates the factors of the compounds that indicate the activity of each compound relative to one of them, to which the activity is attributed, is 1. The compound factor is proportional to the dose of growth inhibition by 50%. In this way. The lower the compound factor, the more active the compound.
For comparison, a known hybrid active compound (compound A) of the formula
og ° -1rG
SOOSNz
The evaluation results are as follows:
Compound No. Compound Factor
eleven
31.1
50.1
120.1
130.6
140.2
150.4
160.9 170.9
300.3
33. 0.5 Compound A 1.2 The data presented indicate a significantly greater efficacy of the proposed compounds compared with the known herbicide.
40
权利要求:
Claims (1)
[1]
Invention Formula
A method of controlling undesirable vegetation by treating it or the soil on which it grows, derivatives of diphenyl ether, characterized in that, in order to increase the herbicidal effect, as a derivative of diphenyl50
Lovogo ether use a compound of the general formula
R 055
where R is chlorine, nitro or cyano; A - CO, CH, С (СН,), (CHjCOO), С (СН,) (СНзО) CHR, -group.
3131А947
in which R, is hydroxyl, dimethylureido, bromine, methyl, C, -Cj-alkoxy, allyloxy, propargyloxy, cyclohexylloxy, methylthio, isopropylthio, 5 2-methoxyethoxy, 2-hydroxy-ethyloxy, 2-chloroethoxy, acetylamino , methylsulfonyl-amino, dimethylamino, 3-4-dn-chlorphenylamino, 1-ethoxycar-0 -bonylethyloxy, acetoxy, pyridyl;
oxygen, NH, N-methyl, N-ethoxycarbonylmethyl, oxygen or sulfur, with ulo-5
qi ro il
in ok pr e si ats
when X is sulfur, then A VII,
CHj, B - oxygen, R - chlorine, the amount of 1-10 kg / ha.
7
4 Priority featured:
02.12.83 - with R - chlorine, nitro, cyano, A - CO, CHj, CH R, R - hydroxyl, bromine, B - oxygen; X is sulfur or oxygen;
05/11/84 - with A - CHR group,
in which R is C, -C, -alkoxy, allyloxy, propargyloxy, methylthio, isopropylthio, 2-methoxyethoxy, 2-chloro-hegyloxy, acetylamino, cyclohexyl-C, methylsulfonylamino, 3,4-dichlorophenylamino, 1-ethoxycarbonyl-ethyloxycetoxy dimethylureido;
11/29/84 - with A, - C (CH,) (CH, 0),
С (СН,) (СН, СОО), СН R, where
R methyl, 2-hydroxyethyloxy, dimethylamino, pyridyl, B - NH, N-methyl, N-ethoxycarbonylmethyl, CH ,.
Table 1,
Chlorine
-sn, -SHVg
-sn -sn / he / -sn (osn) - csm sn, 0
gn
-CH (NHCN; :) b SI,
Nitro Cyano Chlorine
-sn, -CHj-s (o) "
Oxygen |
Sulfur Oxygen
33
-С (СНз) (ОН,)
Continuation of table
Table 2
Continuation of table 3 |
Compiled by R. Streltsov Editor M. Tsitkina Tehred L. Serdyukova Proofreader G. Reshetnik
Order 2223/58 Circulation 630 Subscription
VNIIPI State K. m -; theta of the USSR
for inventions and discoveries 113035, Moscow, Zh-35, Raushsk nab., 4/5
Production and printing company, Uzhgorod, ul.Groektna, 4
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同族专利:
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PH20541A|1987-02-09|
NZ210382A|1989-03-29|
PT79577A|1984-12-01|
EP0145078A2|1985-06-19|
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OA07880A|1986-11-20|
BR8406081A|1985-09-24|
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DK568984A|1985-06-03|
PT79577B|1986-09-11|
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AR240859A1|1991-03-27|
KR920005416B1|1992-07-03|
EP0145078B1|1988-10-12|
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引用文献:
公开号 | 申请日 | 公开日 | 申请人 | 专利标题

JPS5535016A|1978-09-02|1980-03-11|Nippon Nohyaku Co Ltd|Phenoxyphthalate, and herbicide containing the same|
GB8430321D0|1984-11-30|1985-01-09|Shell Int Research|Diphenyl ether herbicides|GB8522528D0|1985-09-11|1985-10-16|Shell Int Research|Diphenyl ether herbicides|
GB8625106D0|1986-10-20|1986-11-26|Shell Int Research|Diphenyl ether herbicides|
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WO1991005781A1|1989-10-12|1991-05-02|Dr. R. Maag Ag|Pyrimidine and triazine derivatives with herbicidal and plant growth regulating properties|
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WO2018049328A1|2016-09-12|2018-03-15|Numerate, Inc.|Bicyclic compounds useful as gpr120 modulators|
EP3509587A4|2016-09-12|2020-03-11|Numerate, Inc.|Monocyclic compounds useful as gpr120 modulators|
法律状态:
优先权:
申请号 | 申请日 | 专利标题
GB838332268A|GB8332268D0|1983-12-02|1983-12-02|Herbicides|
GB848412061A|GB8412061D0|1984-05-11|1984-05-11|Phthalide derivatives|
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